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Page 1
Dichlorido{N-[2-(diphenylphosphanyl)benzylidene]-2-methylaniline}palladium(II) acetonitrile monosolvate.
Motswainyana WM, Onani MO, Jacobs J, Van Meervelt L. Motswainyana WM, et al. Acta Crystallogr C. 2013 Mar;69(Pt 3):209-11. doi: 10.1107/S0108270113002333. Epub 2013 Feb 5. Acta Crystallogr C. 2013. PMID: 23459338
The Pd(II) cation is coordinated by the P and N atoms of the bidentate chelating ligand and by two chloride anions, generating a distorted square-planar coordination geometry. There is a detectable trans influence for the chloride ligands. The methyl group present i …
The Pd(II) cation is coordinated by the P and N atoms of the bidentate chelating ligand and by two chloride anions, generating a dist …
The presence of water improves reductive openings of benzylidene acetals with trimethylaminoborane and aluminium chloride.
Sherman AA, Mironov YV, Yudina ON, Nifantiev NE. Sherman AA, et al. Carbohydr Res. 2003 Apr 4;338(8):697-703. doi: 10.1016/s0008-6215(03)00015-6. Carbohydr Res. 2003. PMID: 12668088
The acidic reagent formed in situ from anhydrous AlCl(3) and H(2)O in 3:1 ratio is much more efficient for the reductive openings of the cyclic benzylidene acetals with Me(3)N x BH(3) in tetrahydrofurane than the AlCl(3) alone. Under proposed conditions, the dioxane-type 4 …
The acidic reagent formed in situ from anhydrous AlCl(3) and H(2)O in 3:1 ratio is much more efficient for the reductive openings of the cyc …
Benzal chloride.
[No authors listed] [No authors listed] IARC Monogr Eval Carcinog Risk Chem Hum. 1982 May;29:65-72. IARC Monogr Eval Carcinog Risk Chem Hum. 1982. PMID: 6813242 No abstract available.
Some observations on the reductive ring opening of 4,6-O-benzylidene acetals of hexopyranosides with the borane trimethylamine-aluminium chloride reagent.
Daragics K, Szabó P, Fügedi P. Daragics K, et al. Carbohydr Res. 2011 Sep 6;346(12):1633-7. doi: 10.1016/j.carres.2011.04.046. Epub 2011 May 3. Carbohydr Res. 2011. PMID: 21601182
Reductive ring openings of 3-O-benzoyl-4,6-O-benzylidene-D-glucopyranosides with BH(3).NMe(3)-AlCl(3) are accompanied by side reactions, such as debenzoylation and reduction of the benzoate to benzyl ether. ...
Reductive ring openings of 3-O-benzoyl-4,6-O-benzylidene-D-glucopyranosides with BH(3).NMe(3)-AlCl(3) are accompanied by side reactio …
Pyridine as trigger for chloride isomerisation in chelated ruthenium benzylidene complexes: implications for olefin metathesis.
Zirngast M, Pump E, Leitgeb A, Albering JH, Slugovc C. Zirngast M, et al. Chem Commun (Camb). 2011 Feb 28;47(8):2261-3. doi: 10.1039/c0cc04897f. Epub 2011 Jan 21. Chem Commun (Camb). 2011. PMID: 21253629
The cationic pyridine adduct of a ruthenium complex bearing a chelating benzylidene and an N-heterocyclic carbene was identified as an intermediate during the activation of cis dichloro species and a novel triggering concept for olefin metathesis catalysts based on cationi …
The cationic pyridine adduct of a ruthenium complex bearing a chelating benzylidene and an N-heterocyclic carbene was identified as a …
Some benzylidene acetal derivatives of theophylline nucleosides.
Freestone AJ, Hough L, Richardson AC. Freestone AJ, et al. Carbohydr Res. 1975 Dec;45:3-9. doi: 10.1016/s0008-6215(00)85860-7. Carbohydr Res. 1975. PMID: 1212671
The reaction of some hexopyranosyltheophylline nucleosides with benzaldehyde in the presence of zinc chloride gave the expected benzylidene acetals. Thus, 7-alpha-D-mannopyranosyltheophylline gave the 2',3':4',6'-diacetal as a mixture of diastereoisomers, one of whi …
The reaction of some hexopyranosyltheophylline nucleosides with benzaldehyde in the presence of zinc chloride gave the expected be …
Carcinogenicity of benzyl chloride, benzal chloride, benzotrichloride and benzoyl chloride in mice by skin application.
Fukuda K, Matsushita H, Sakabe H, Takemoto K. Fukuda K, et al. Gan. 1981 Oct;72(5):655-64. Gan. 1981. PMID: 7327367
The carcinogenicity of benzyl chloride (BYC), benzal chloride (BAC), benzotrichloride (BTC) and benzoyl chloride (BOC), which were suspected as causative agents of lung cancer and maxillary malignant lymphoma of workers employed in factories producing BOC, wa …
The carcinogenicity of benzyl chloride (BYC), benzal chloride (BAC), benzotrichloride (BTC) and benzoyl chloride (BOC), …
Cyanuric chloride/sodium borohydride: a new reagent combination for reductive opening of 4,6-benzylidene acetals of carbohydrates to primary alcohols.
Tatina M, Yousuf SK, Aravinda S, Singh B, Mukherjee D. Tatina M, et al. Carbohydr Res. 2013 Nov 15;381:142-5. doi: 10.1016/j.carres.2013.09.003. Epub 2013 Sep 13. Carbohydr Res. 2013. PMID: 24103734
In the first such example, NaBH4 in combination with cyanuric chloride (TCT) has been used to obtain 6-hydroxy-4-benzyl ether derivatives from 4,6-benzylidene acetals of carbohydrates. ...
In the first such example, NaBH4 in combination with cyanuric chloride (TCT) has been used to obtain 6-hydroxy-4-benzyl ether derivat …
Substituent Effects on the Ultraviolet Absorption Properties of 2,4-Dihydroxy Dibenzophenone.
Wu F, Tan S, Fang Z, Deng J, He Z, Huang C, Au C, Yi B. Wu F, et al. Molecules. 2022 Nov 24;27(23):8169. doi: 10.3390/molecules27238169. Molecules. 2022. PMID: 36500263 Free PMC article.
Nine compounds of 2,4-dihydroxy dibenzophenone with different substituents were prepared by a solvent-free reaction of benzoyl chloride. The maximum absorption wavelength (lambda(max)) of these samples was measured, and their UV resistance properties in cotton fabric as we …
Nine compounds of 2,4-dihydroxy dibenzophenone with different substituents were prepared by a solvent-free reaction of benzoyl chloride …
128 results